Nana the First! is a reprint of volumes 2, 3, 4, and 5 to promote the release of Nana 2.
The book includes chapters one through sixteen of the original manga. Some of the pages are also in color. Various articles on Nana 2 and a "talk session featuring director, Kentaro Otani, Ai Yazawa, Mika Nakashima (Nana Osaki) and Yui Ichikawa (Nana Komatsu) are shown. An interview with the anime director, Morio Asaka and some voice actors is also included.